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Synthesis and characterisation of advanced molecules with implemented adamantane skeleton
Jančík, Ján ; Maier,, Lukáš (referee) ; Krajčovič, Jozef (advisor)
This diploma thesis describes synthetic approach and characterization of advanced molecules with implemented adamantane skeleton and perspective use in attractive field of organic electronics. Three of four prepared molecules based on para-bis(2-thienyl)phenylene are original and totally new, and there were performed different synthetic approaches with comparison of yield, ecological and financial impact. Study of microwave synthetic approach was provided for cross-coupling reactions on para-bis(2-thienyl)phenylene skeleton. For all molecules were used ethyladamantyl and methyladamantyl substituents. Also, two completely new molecules based on 2,2':5',2''-terthiophene with ethyladamantyl and methyladamantyl substituents were prepared. In the next part were prepared new dimer structures of adamantane with possible application on field of polymers as bridge molecules. In the thesis were also made series of experiments for preparation of tetrasubstituted adamantane molecules, and for optimisation of preparation of spiroadamantane systems.
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IMPLEMETATION OF POLYCYCLIC SATURATED SYSTEMS IN ADVANCED SMART MOLECULES USABLE IN ORGANIC ELECTRONICS
Jančík, Ján ; Richtár, Jan (referee) ; Krajčovič, Jozef (advisor)
This essay deals with implementation of polycyclic saturated systems as bulky and very stable molecules, in advanced systems usable in organic electronics. It deals with theoretical aspects of structure and properties of polycyclic saturated systems, which based on available examples and literature are very perspective. Based on theoretical aspect in the first part of essay, the second part deals with synthesis of new molecule with incorporation of polycyclic saturated system usable in organic electronics. This part deals with all main intermediates synthetized via cross-coupling reactions.
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Synthesis and characterisation of advanced molecules with implemented adamantane skeleton
Jančík, Ján ; Maier,, Lukáš (referee) ; Krajčovič, Jozef (advisor)
This diploma thesis describes synthetic approach and characterization of advanced molecules with implemented adamantane skeleton and perspective use in attractive field of organic electronics. Three of four prepared molecules based on para-bis(2-thienyl)phenylene are original and totally new, and there were performed different synthetic approaches with comparison of yield, ecological and financial impact. Study of microwave synthetic approach was provided for cross-coupling reactions on para-bis(2-thienyl)phenylene skeleton. For all molecules were used ethyladamantyl and methyladamantyl substituents. Also, two completely new molecules based on 2,2':5',2''-terthiophene with ethyladamantyl and methyladamantyl substituents were prepared. In the next part were prepared new dimer structures of adamantane with possible application on field of polymers as bridge molecules. In the thesis were also made series of experiments for preparation of tetrasubstituted adamantane molecules, and for optimisation of preparation of spiroadamantane systems.
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IMPLEMETATION OF POLYCYCLIC SATURATED SYSTEMS IN ADVANCED SMART MOLECULES USABLE IN ORGANIC ELECTRONICS
Jančík, Ján ; Richtár, Jan (referee) ; Krajčovič, Jozef (advisor)
This essay deals with implementation of polycyclic saturated systems as bulky and very stable molecules, in advanced systems usable in organic electronics. It deals with theoretical aspects of structure and properties of polycyclic saturated systems, which based on available examples and literature are very perspective. Based on theoretical aspect in the first part of essay, the second part deals with synthesis of new molecule with incorporation of polycyclic saturated system usable in organic electronics. This part deals with all main intermediates synthetized via cross-coupling reactions.
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